Dissecting Anion Effects in Gold(I)-Catalyzed Intermolecular Cycloadditions

From a series of gold complexes of the type [t-BuXPhosAu(MeCN)]X (X=anion), the best results in intermolecular gold(I)-catalyzed reactions are obtained with the complex with the bulky and soft anion BAr(4)(F−) [BAr(4)(F−)=3,5-bis(trifluoromethyl)phenylborate] improving the original protocols by 10–3...

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Detalles Bibliográficos
Autores principales: Homs, Anna, Obradors, Carla, Lebœuf, David, Echavarren, Antonio M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Updates
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4498468/
https://www.ncbi.nlm.nih.gov/pubmed/26190958
http://dx.doi.org/10.1002/adsc.201300704

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4498468/
https://www.ncbi.nlm.nih.gov/pubmed/26190958
http://dx.doi.org/10.1002/adsc.201300704

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