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Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications**

Rate coefficients are directly determined for the reactions of the Criegee intermediates (CI) CH(2)OO and CH(3)CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and acetic acid (CH(3)COOH), employing two complementary techniques: multiplexed photoionization mass spectrometry and cavit...

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Detalles Bibliográficos
Autores principales: Welz, Oliver, Eskola, Arkke J, Sheps, Leonid, Rotavera, Brandon, Savee, John D, Scheer, Adam M, Osborn, David L, Lowe, Douglas, Murray Booth, A, Xiao, Ping, Anwar H Khan, M, Percival, Carl J, Shallcross, Dudley E, Taatjes, Craig A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499262/
https://www.ncbi.nlm.nih.gov/pubmed/24668781
http://dx.doi.org/10.1002/anie.201400964