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Rate Coefficients of C1 and C2 Criegee Intermediate Reactions with Formic and Acetic Acid Near the Collision Limit: Direct Kinetics Measurements and Atmospheric Implications**
Rate coefficients are directly determined for the reactions of the Criegee intermediates (CI) CH(2)OO and CH(3)CHOO with the two simplest carboxylic acids, formic acid (HCOOH) and acetic acid (CH(3)COOH), employing two complementary techniques: multiplexed photoionization mass spectrometry and cavit...
Autores principales: | Welz, Oliver, Eskola, Arkke J, Sheps, Leonid, Rotavera, Brandon, Savee, John D, Scheer, Adam M, Osborn, David L, Lowe, Douglas, Murray Booth, A, Xiao, Ping, Anwar H Khan, M, Percival, Carl J, Shallcross, Dudley E, Taatjes, Craig A |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499262/ https://www.ncbi.nlm.nih.gov/pubmed/24668781 http://dx.doi.org/10.1002/anie.201400964 |
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