Metal-Size Influence in Iso-Selective Lactide Polymerization**

Iso-selective initiators for the ring-opening polymerization (ROP) of rac-lactide are rare outside of Group 13. We describe the first examples of highly iso-selective lutetium initiators. The phosphasalen lutetium ethoxide complex shows excellent iso-selectivity, with a P(i) value of 0.81–0.84 at 29...

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Detalles Bibliográficos
Autores principales: Bakewell, Clare, White, Andrew J P, Long, Nicholas J, Williams, Charlotte K
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499264/
https://www.ncbi.nlm.nih.gov/pubmed/25044165
http://dx.doi.org/10.1002/anie.201403643

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499264/
https://www.ncbi.nlm.nih.gov/pubmed/25044165
http://dx.doi.org/10.1002/anie.201403643

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