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Metal-Size Influence in Iso-Selective Lactide Polymerization**

Iso-selective initiators for the ring-opening polymerization (ROP) of rac-lactide are rare outside of Group 13. We describe the first examples of highly iso-selective lutetium initiators. The phosphasalen lutetium ethoxide complex shows excellent iso-selectivity, with a P(i) value of 0.81–0.84 at 29...

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Detalles Bibliográficos
Autores principales:	Bakewell, Clare, White, Andrew J P, Long, Nicholas J, Williams, Charlotte K
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2014
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4499264/ https://www.ncbi.nlm.nih.gov/pubmed/25044165 http://dx.doi.org/10.1002/anie.201403643

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