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Crossed McMurry Coupling Reactions for Porphycenic Macrocycles: Non-Statistical Selectivity and Rationalisation

Crossed McMurry reactions of bifuran- or bithiophenedicarbaldehydes with bipyrroledicarbaldehydes have been studied for the first time. Only those porphycenic macrocycles derived from homocoupled McMurry products were formed. The results are explained by using both density functional theory and elec...

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Detalles Bibliográficos
Autores principales: Cowie, Thomas Y, Kennedy, Lorna, Żurek, Justyna M, Paterson, Martin J, Bebbington, Magnus W P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4502767/
https://www.ncbi.nlm.nih.gov/pubmed/26213484
http://dx.doi.org/10.1002/ejoc.201500221