A Simple and Highly Effective Ligand System for the Copper(I)-Mediated Assembly of Rotaxanes**

A [2]rotaxane was produced through the assembly of a picolinaldehyde, an amine, and a bipyridine macrocycle around a Cu(I) template by imine bond formation in close-to-quantitative yield. An analogous [3]rotaxane is obtained in excellent yield by replacing the amine with a diamine, thus showing the...

Descripción completa

Detalles Bibliográficos
Autores principales: Campbell, Christopher J, Leigh, David A, Vitorica-Yrezabal, Inigo J, Woltering, Steffen L
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4502974/
https://www.ncbi.nlm.nih.gov/pubmed/25314000
http://dx.doi.org/10.1002/anie.201407817

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4502974/
https://www.ncbi.nlm.nih.gov/pubmed/25314000
http://dx.doi.org/10.1002/anie.201407817

Ejemplares similares