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Stable and catalytically active iron porphyrin-based porous organic polymer: Activity as both a redox and Lewis acid catalyst

A new porphyrin-based porous organic polymer (POP) with BET surface area ranging from 780 to 880 m(2)/g was synthesized in free-base form via the reaction of meso-tetrakis(pentafluorophenyl) porphyrin and a rigid trigonal building block, hexahydroxytriphenylene. The material was then metallated with...

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Detalles Bibliográficos
Autores principales: Oveisi, Ali R., Zhang, Kainan, Khorramabadi-zad, Ahmad, Farha, Omar K., Hupp, Joseph T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4503946/
https://www.ncbi.nlm.nih.gov/pubmed/26177563
http://dx.doi.org/10.1038/srep10621