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Identification of an Isothiocyanate on the HypEF Complex Suggests a Route for Efficient Cyanyl–Group Channeling during [NiFe]–Hydrogenase Cofactor Generation

[NiFe]–hydrogenases catalyze uptake and evolution of H(2) in a wide range of microorganisms. The enzyme is characterized by an inorganic nickel/ iron cofactor, the latter of which carries carbon monoxide and cyanide ligands. In vivo generation of these ligands requires a number of auxiliary proteins...

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Detalles Bibliográficos
Autores principales: Stripp, Sven T., Lindenstrauss, Ute, Sawers, R. Gary, Soboh, Basem
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Public Library of Science 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4506123/
https://www.ncbi.nlm.nih.gov/pubmed/26186649
http://dx.doi.org/10.1371/journal.pone.0133118