Phosphide Delivery to a Cyclotrisilene**

The reactivity of the 2-phosphaethynolate anion (PCO(−)) towards a cyclic trisilene (cSi(3)(Tip)(4)) is reported. The result is the net activation of the P=C and Si=Si multiple bonds of the precursors affording a heteroatomic bicyclo[1.1.1]pentan-2-one analogue ([P(CO)Si(3)(Tip)(4)](−); 1). This rea...

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Detalles Bibliográficos
Autores principales: Robinson, Thomas P, Cowley, Michael J, Scheschkewitz, David, Goicoechea, Jose M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4506556/
https://www.ncbi.nlm.nih.gov/pubmed/25418506
http://dx.doi.org/10.1002/anie.201409908

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4506556/
https://www.ncbi.nlm.nih.gov/pubmed/25418506
http://dx.doi.org/10.1002/anie.201409908

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