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Phosphide Delivery to a Cyclotrisilene**
The reactivity of the 2-phosphaethynolate anion (PCO(−)) towards a cyclic trisilene (cSi(3)(Tip)(4)) is reported. The result is the net activation of the P=C and Si=Si multiple bonds of the precursors affording a heteroatomic bicyclo[1.1.1]pentan-2-one analogue ([P(CO)Si(3)(Tip)(4)](−); 1). This rea...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
WILEY-VCH Verlag
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4506556/ https://www.ncbi.nlm.nih.gov/pubmed/25418506 http://dx.doi.org/10.1002/anie.201409908 |