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Computational Prediction of One-Step Synthesis of Seven-membered Fused Rings by (5+2) Cycloaddition Utilising Cycloalkenes

The (5+2) cycloaddition reaction utilising cycloalkenes is rare, although it is one of the most efficient methods of constructing seven-membered fused rings because of its high atom- and step-economy. In this study, we used quantum mechanical calculations to predict the plausibility of using the Rh-...

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Detalles Bibliográficos
Autores principales: Zhou, Chen-Chen, Ke, Xiao-Na, Xu, Xiu-Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4510518/
https://www.ncbi.nlm.nih.gov/pubmed/26198317
http://dx.doi.org/10.1038/srep12272