Characterizing Pressure-Induced Uranium C=H Agostic Bonds**

The diuranium(III) compound [UN′′(2)](2)(μ-η(6):η(6)-C(6)H(6)) (N′′=N(SiMe(3))(2)) has been studied using variable, high-pressure single-crystal X-ray crystallography, and density functional theory. In this compound, the low-coordinate metal cations are coupled through π- and δ-symmetric arene overl...

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Detalles Bibliográficos
Autores principales: Arnold, Polly L, Prescimone, Alessandro, Farnaby, Joy H, Mansell, Stephen M, Parsons, Simon, Kaltsoyannis, Nikolas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4515102/
https://www.ncbi.nlm.nih.gov/pubmed/25882329
http://dx.doi.org/10.1002/anie.201411250

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4515102/
https://www.ncbi.nlm.nih.gov/pubmed/25882329
http://dx.doi.org/10.1002/anie.201411250

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