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Gold(I)-Catalysed Direct Thioetherifications Using Allylic Alcohols: an Experimental and Computational Study

A gold(I)-catalysed direct thioetherification reaction between allylic alcohols and thiols is presented. The reaction is generally highly regioselective (S(N)2′). This dehydrative allylation procedure is very mild and atom economical, producing only water as the by-product and avoiding any unnecessa...

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Detalles Bibliográficos
Autores principales: Herkert, Lorena, Green, Samantha L J, Barker, Graeme, Johnson, David G, Young, Paul C, Macgregor, Stuart A, Lee, Ai-Lan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4517163/
https://www.ncbi.nlm.nih.gov/pubmed/25080400
http://dx.doi.org/10.1002/chem.201403293