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Anion Sensing by Solution- and Surface-Assembled Osmium(II) Bipyridyl Rotaxanes

We report the preparation of [2]rotaxanes containing an electrochemically and optically active osmium(II) bipyridyl macrocyclic component mechanically bonded with cationic pyridinium axles. Such interlocked host systems are demonstrated to recognise and sense anionic guest species as shown by (1)H N...

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Detalles Bibliográficos
Autores principales: Lehr, Joshua, Lang, Thomas, Blackburn, Octavia A, Barendt, Timothy A, Faulkner, Stephen, Davis, Jason J, Beer, Paul D
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4517173/
https://www.ncbi.nlm.nih.gov/pubmed/24127251
http://dx.doi.org/10.1002/chem.201302886