Rh-catalyzed decarbonylation of conjugated ynones via carbon–alkyne bond activation: reaction scope and mechanistic exploration via DFT calculations

In this full article, detailed development of a catalytic decarbonylation of conjugated monoynones to synthesize disubstituted alkynes is described. The reaction scope and limitation has been thoroughly investigated, and a broad range of functional groups including heterocycles were compatible under...

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Detalles Bibliográficos
Autores principales: Dermenci, Alpay, Whittaker, Rachel E., Gao, Yang, Cruz, Faben A., Yu, Zhi-Xiang, Dong, Guangbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4517480/
https://www.ncbi.nlm.nih.gov/pubmed/26229587
http://dx.doi.org/10.1039/c5sc00584a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4517480/
https://www.ncbi.nlm.nih.gov/pubmed/26229587
http://dx.doi.org/10.1039/c5sc00584a

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