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Crystal structures of 4-chloro­pyridine-2-carbo­nitrile and 6-chloro­pyridine-2-carbo­nitrile exhibit different inter­molecular π-stacking, C—H⋯N(nitrile) and C—H⋯N(pyridine) inter­actions

The two title compounds are isomers of C(6)H(3)ClN(2) containing a pyridine ring, a nitrile group, and a chloro substituent. The mol­ecules of each compound pack together in the solid state with offset face-to-face π-stacking, and inter­molecular C—H⋯N(nitrile) and C—H⋯N(pyridine) inter­actions. 4-C...

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Detalles Bibliográficos
Autores principales: Montgomery, Matthew J., O’Connor, Thomas J., Tanski, Joseph M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4518955/
https://www.ncbi.nlm.nih.gov/pubmed/26279884
http://dx.doi.org/10.1107/S2056989015011767