The Role of Aromaticity, Hybridization, Electrostatics, and Covalency in Resonance-Assisted Hydrogen Bonds of Adenine–Thymine (AT) Base Pairs and Their Mimics

Hydrogen bonds play a crucial role in many biochemical processes and in supramolecular chemistry. In this study, we show quantum chemically that neither aromaticity nor other forms of π assistance are responsible for the enhanced stability of the hydrogen bonds in adenine–thymine (AT) DNA base pairs...

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Detalles Bibliográficos
Autores principales: Guillaumes, L, Simon, S, Fonseca Guerra, C
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley & Sons, Ltd 2015
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4522182/
https://www.ncbi.nlm.nih.gov/pubmed/26246994
http://dx.doi.org/10.1002/open.201402132

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4522182/
https://www.ncbi.nlm.nih.gov/pubmed/26246994
http://dx.doi.org/10.1002/open.201402132

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