Cargando…

Atom-Efficient Gold(I)-Chloride-Catalyzed Synthesis of α-Sulfenylated Carbonyl Compounds from Propargylic Alcohols and Aryl Thiols: Substrate Scope and Experimental and Theoretical Mechanistic Investigation

Gold(I)-chloride-catalyzed synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols showed a wide substrate scope with respect to both propargylic alcohols and aryl thiols. Primary and secondary aromatic propargylic alcohols generated α-sulfenylated aldehydes and keto...

Descripción completa

Detalles Bibliográficos
Autores principales: Biswas, Srijit, Dahlstrand, Christian, Watile, Rahul A, Kalek, Marcin, Himo, Fahmi, Samec, Joseph S M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4524420/
https://www.ncbi.nlm.nih.gov/pubmed/24272980
http://dx.doi.org/10.1002/chem.201302485