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Atropisomeric [(diphosphine)Au(2)Cl(2)] Complexes and their Catalytic Activity Towards Asymmetric Cycloisomerisation of 1,6-Enynes

X-ray crystal structures of two [(diphosphine)Au(2)Cl(2)] complexes (in which diphosphine=P-Phos and xylyl-P-Phos; P-Phos=[2,2′,6,6′-Tetramethoxy-4,4′-bis(diphenylphosphino)-3,3′-bipyridine]) were determined and compared to the reported structures of similar atropisomeric gold complexes. Correlation...

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Detalles Bibliográficos
Autores principales: Barreiro, Elena M, Boltukhina, Ekaterina V, White, Andrew J P, Hii, King Kuok (Mimi)
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4524423/
https://www.ncbi.nlm.nih.gov/pubmed/25504519
http://dx.doi.org/10.1002/chem.201404496