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Gold-Catalyzed Reactions via Cyclopropyl Gold Carbene-like Intermediates
[Image: see text] Cycloisomerizations of 1,n-enynes catalyzed by gold(I) proceed via electrophilic species with a highly distorted cyclopropyl gold(I) carbene-like structure, which can react with different nucleophiles to form a wide variety of products by attack at the cyclopropane or the carbene c...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4531321/ https://www.ncbi.nlm.nih.gov/pubmed/26061916 http://dx.doi.org/10.1021/acs.joc.5b01106 |