Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H(2) Oxidation by a NiFe Hydrogenase**

A novel in situ IR spectroscopic approach is demonstrated for the characterization of hydrogenase during catalytic turnover. E. coli hydrogenase 1 (Hyd-1) is adsorbed on a high surface-area carbon electrode and subjected to the same electrochemical control and efficient supply of substrate as in pro...

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Detalles Bibliográficos
Autores principales: Hidalgo, Ricardo, Ash, Philip A, Healy, Adam J, Vincent, Kylie A
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4531817/
https://www.ncbi.nlm.nih.gov/pubmed/25925315
http://dx.doi.org/10.1002/anie.201502338

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4531817/
https://www.ncbi.nlm.nih.gov/pubmed/25925315
http://dx.doi.org/10.1002/anie.201502338

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