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Infrared Spectroscopy During Electrocatalytic Turnover Reveals the Ni-L Active Site State During H(2) Oxidation by a NiFe Hydrogenase**

A novel in situ IR spectroscopic approach is demonstrated for the characterization of hydrogenase during catalytic turnover. E. coli hydrogenase 1 (Hyd-1) is adsorbed on a high surface-area carbon electrode and subjected to the same electrochemical control and efficient supply of substrate as in pro...

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Detalles Bibliográficos
Autores principales:	Hidalgo, Ricardo, Ash, Philip A, Healy, Adam J, Vincent, Kylie A
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4531817/ https://www.ncbi.nlm.nih.gov/pubmed/25925315 http://dx.doi.org/10.1002/anie.201502338

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