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Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes**
A Rh-catalyst system based on the asymmetric ligand (t)Bu(2)PCH(2)P(o-C(6)H(4)OMe)(2) is reported that allows for the hydroacylation of challenging internal alkenes with β-substituted aldehydes. Mechanistic studies point to the stabilizing role of both excess alkene and the OMe-group.
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4531818/ https://www.ncbi.nlm.nih.gov/pubmed/26069052 http://dx.doi.org/10.1002/anie.201503208 |