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Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes**

A Rh-catalyst system based on the asymmetric ligand (t)Bu(2)PCH(2)P(o-C(6)H(4)OMe)(2) is reported that allows for the hydroacylation of challenging internal alkenes with β-substituted aldehydes. Mechanistic studies point to the stabilizing role of both excess alkene and the OMe-group.

Detalles Bibliográficos
Autores principales:	Prades, Amparo, Fernández, Maitane, Pike, Sebastian D, Willis, Michael C, Weller, Andrew S
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	WILEY-VCH Verlag 2015
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4531818/ https://www.ncbi.nlm.nih.gov/pubmed/26069052 http://dx.doi.org/10.1002/anie.201503208

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