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Wagner–Meerwein-Type Rearrangements of Germapolysilanes - A Stable Ion Study
[Image: see text] The rearrangement of tris(trimethylsilyl)silyltrimethylgermane 1 to give tetrakis(trimethylsilyl)germane 2 was investigated as a typical example for Lewis acid catalyzed Wagner–Meerwein-type rearrangements of polysilanes and polygermasilanes. Direct (29)Si NMR spectroscopic evidenc...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2015
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4534834/ https://www.ncbi.nlm.nih.gov/pubmed/26294805 http://dx.doi.org/10.1021/acs.organomet.5b00431 |