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Wagner–Meerwein-Type Rearrangements of Germapolysilanes - A Stable Ion Study

[Image: see text] The rearrangement of tris(trimethylsilyl)silyltrimethylgermane 1 to give tetrakis(trimethylsilyl)germane 2 was investigated as a typical example for Lewis acid catalyzed Wagner–Meerwein-type rearrangements of polysilanes and polygermasilanes. Direct (29)Si NMR spectroscopic evidenc...

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Detalles Bibliográficos
Autores principales: Albers, Lena, Meshgi, Mohammad Aghazadeh, Baumgartner, Judith, Marschner, Christoph, Müller, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4534834/
https://www.ncbi.nlm.nih.gov/pubmed/26294805
http://dx.doi.org/10.1021/acs.organomet.5b00431

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