Macromolecular Design via an Organocatalytic, Monomer-Specific and Temperature-Dependent “On/Off Switch”. High Precision Synthesis of Polyester/Polycarbonate Multiblock Copolymers

[Image: see text] The employment of a monomer-specific “on/off switch” was used to synthesize a nine-block copolymer with a predetermined molecular weight and narrow distribution (Đ = 1.26) in only 2.5 h. The monomers consisted of a six-membered cyclic carbonate (i.e., 2-allyloxymethyl-2-ethyl-trime...

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Detalles Bibliográficos
Autores principales: Olsén, Peter, Odelius, Karin, Keul, Helmut, Albertsson, Ann-Christine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4535708/
https://www.ncbi.nlm.nih.gov/pubmed/26294800
http://dx.doi.org/10.1021/acs.macromol.5b00254

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4535708/
https://www.ncbi.nlm.nih.gov/pubmed/26294800
http://dx.doi.org/10.1021/acs.macromol.5b00254

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