Cargando…

N-Heterocyclic Olefins as Organocatalysts for Polymerization: Preparation of Well-Defined Poly(propylene oxide)**

The metal-free polymerization of propylene oxide (PO) using a special class of alkene—N-heterocyclic olefins (NHOs)—as catalysts is described. Manipulation of the chemical structure of the NHO organocatalyst allows for the preparation of the poly(propylene oxide) in high yields with high turnover (T...

Descripción completa

Detalles Bibliográficos
Autores principales: Naumann, Stefan, Thomas, Anthony W, Dove, Andrew P
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4539597/
https://www.ncbi.nlm.nih.gov/pubmed/26136456
http://dx.doi.org/10.1002/anie.201504175