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A fluorescent paramagnetic Mn metal–organic framework based on semi-rigid pyrene tetra­carboxylic acid: sensing of solvent polarity and explosive nitroaromatics

An Mn metal–organic framework (Mn-MOF), Mn-L, based on a pyrene-tetraacid linker (H(4) L), displays a respectable fluorescence quantum yield of 8.3% in spite of the presence of the paramagnetic metal ions, due presumably to fixation of the metal ions in geometries that do not allow complete energy/c...

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Detalles Bibliográficos
Autores principales: Bajpai, Alankriti, Mukhopadhyay, Arindam, Krishna, Manchugondanahalli Shivakumar, Govardhan, Savitha, Moorthy, Jarugu Narasimha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4547823/
https://www.ncbi.nlm.nih.gov/pubmed/26306197
http://dx.doi.org/10.1107/S2052252515012506