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Crystal structure of potassium sodium heptahydrogen hexamolybdocobaltate(III) octahydrate: an extra-protonated B-series Anderson-type heteropolyoxidometalate
The title compound, KNa[Co(III)(OH)(7){Mo(6)O(17)}]·8H(2)O, was obtained by the ion-exchange technique from K(3)[Co(μ(3)-OH)(6)Mo(6)O(18)]·7H(2)O. Six μ(3)-O atoms and one O atom of the bridging μ(2)-O atom are protonated. This novel polyanion protonated by an extra H atom is an unexpected polyanion...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555401/ https://www.ncbi.nlm.nih.gov/pubmed/26396841 http://dx.doi.org/10.1107/S2056989015014784 |