Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts

[Image: see text] A catalytic enantioselective and regiodivergent arylation of alkenes is described. Chiral copper(II)bisoxazoline complexes catalyze the addition of diaryliodonium salts to allylic amides in excellent ee. Moreover, the arylation can be controlled by the electronic nature of the diar...

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Detalles Bibliográficos
Autores principales: Cahard, Elise, Male, Henry P. J., Tissot, Matthieu, Gaunt, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4569064/
https://www.ncbi.nlm.nih.gov/pubmed/26090564
http://dx.doi.org/10.1021/jacs.5b03937

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4569064/
https://www.ncbi.nlm.nih.gov/pubmed/26090564
http://dx.doi.org/10.1021/jacs.5b03937

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