Crystal structure of [1,1′′′-bis­(pyrimidin-2-yl)-4,4′:2′,2′′:4′′,4′′′-quaterpyridine-1,1′′′-diium-κ(2) N (1′),N (1′′)]bis­[2-(pyridin-2-yl)phenyl-κ(2) N,C (1)]iridium(III) tris­(hexa­fluorido­phosphate) aceto­nitrile tris­olvate

In the title compound, [Ir(C(11)H(8)N)(2)(C(28)H(20)N(8))](PF(6))(3)·3CH(3)CN or [Ir(III)(ppy)(2){(2-pym)(2)qpy(2+)}](PF(6))(3)·3CH(3)CN (ppy = deprotonated 2-phenyl­pyridine, pym = pyrimidyl and qpy = 4,4′:2′,2′′:4′′,4′′′-quaterpyrid­yl), the Ir(3+) cation is coordinated by two C atoms and four N a...

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Detalles Bibliográficos
Autores principales: Coe, Benjamin J., Peers, Martyn K., Raftery, James, Scrutton, Nigel S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571346/
https://www.ncbi.nlm.nih.gov/pubmed/26396745
http://dx.doi.org/10.1107/S2056989015012463

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571346/
https://www.ncbi.nlm.nih.gov/pubmed/26396745
http://dx.doi.org/10.1107/S2056989015012463

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