Crystal structures of di­iodido­bis­[(1S,5S)-4-mesityl-1,2,8,8-tetra­methyl-2,4-di­aza­bicyclo­[3.2.1]octan-3-yl­idene-κC (3)]palladium(IV) and di­chlorido­[(1S,5S)-4-mesityl-1,2,8,8-tetra­methyl-2,4-di­aza­bicyclo[3.2.1]octan-3-yl­idene-κC (3)](tri­phenyl­phosphane-κP)palladium(IV)

The mol­ecular structures of the chiral title compounds, [Pd(C(19)H(28)N(2))(2)I(2)], (I), and [Pd(C(19)H(28)N(2))Cl(2)(C(18)H(15)P)], (II), show a distorted square-planar coordination around the Pd(II) atoms with two halogenide (Hal) ligands each and two N-heterocyclic carbene (NHC) ligands in (I)...

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Detalles Bibliográficos
Autores principales: Rais, Eduard, Flörke, Ulrich, Wilhelm, René
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571356/
https://www.ncbi.nlm.nih.gov/pubmed/26396755
http://dx.doi.org/10.1107/S2056989015013055

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571356/
https://www.ncbi.nlm.nih.gov/pubmed/26396755
http://dx.doi.org/10.1107/S2056989015013055

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