Structure and conformational analysis of spiroketals from 6-O-methyl-9(E)-hydroxyiminoerythronolide A

Three novel spiroketals were prepared by a one-pot transformation of 6-O-methyl-9(E)-hydroxyiminoerythronolide A. We present the formation of a [4.5]spiroketal moiety within the macrolide lactone ring, but also the unexpected formation of a 10-C=11-C double bond and spontaneous change of stereochemi...

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Detalles Bibliográficos
Autores principales: Čikoš, Ana, Ćaleta, Irena, Žiher, Dinko, Vine, Mark B, Elenkov, Ivaylo J, Dukši, Marko, Gembarovski, Dubravka, Ilijaš, Marina, Dragojević, Snježana, Malnar, Ivica, Alihodžić, Sulejman
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578343/
https://www.ncbi.nlm.nih.gov/pubmed/26425201
http://dx.doi.org/10.3762/bjoc.11.157

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578343/
https://www.ncbi.nlm.nih.gov/pubmed/26425201
http://dx.doi.org/10.3762/bjoc.11.157

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