Pyridine-promoted dediazoniation of aryldiazonium tetrafluoroborates: Application to the synthesis of SF(5)-substituted phenylboronic esters and iodobenzenes

Pyridine promotes dediazoniation of aryldiazonium tetrafluoroborates. The formed aryl radicals were trapped with B(2)pin(2), iodine, or tetrahydrofuran to afford boronic esters, iodobenzenes and benzenes, respectively. The application to the synthesis of (pentafluorosulfanyl)phenylboronic esters, io...

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Detalles Bibliográficos
Autores principales: Iakobson, George, Du, Junyi, Slawin, Alexandra M Z, Beier, Petr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578358/
https://www.ncbi.nlm.nih.gov/pubmed/26425206
http://dx.doi.org/10.3762/bjoc.11.162

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578358/
https://www.ncbi.nlm.nih.gov/pubmed/26425206
http://dx.doi.org/10.3762/bjoc.11.162

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