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Qualitative evaluation of regioselectivity in the formation of di- and tri-6-O-tritylates of α-cyclodextrin

The quantitative analysis of reaction products showed that the reaction of 6(A),6(D)-di-O-trityl-α-cyclodextrin (CD), AD-isomer, with trityl chloride in pyridine at 55 °C gave 6(A),6(B),6(E)-tri-O-trityl-α-CD, the amount of which was only 25% of that of simultaneously formed 6(A),6(B),6(D)-tri-O-tri...

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Detalles Bibliográficos
Autores principales: Yoshikiyo, Keisuke, Matsui, Yoshihisa, Yamamoto, Tatsuyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578407/
https://www.ncbi.nlm.nih.gov/pubmed/26425212
http://dx.doi.org/10.3762/bjoc.11.168