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A novel and widespread class of ketosynthase is responsible for the head-to-head condensation of two acyl moieties in bacterial pyrone biosynthesis

The biosynthesis of photopyrones, novel quorum sensing signals in Photorhabdus, has been studied by heterologous expression of the photopyrone synthase PpyS catalyzing the head-to-head condensation of two acyl moieties. The biochemical mechanism of pyrone formation has been investigated by amino aci...

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Detalles Bibliográficos
Autores principales: Kresovic, Darko, Schempp, Florence, Cheikh-Ali, Zakaria, Bode, Helge B
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578411/
https://www.ncbi.nlm.nih.gov/pubmed/26425196
http://dx.doi.org/10.3762/bjoc.11.152