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A novel and widespread class of ketosynthase is responsible for the head-to-head condensation of two acyl moieties in bacterial pyrone biosynthesis
The biosynthesis of photopyrones, novel quorum sensing signals in Photorhabdus, has been studied by heterologous expression of the photopyrone synthase PpyS catalyzing the head-to-head condensation of two acyl moieties. The biochemical mechanism of pyrone formation has been investigated by amino aci...
Autores principales: | Kresovic, Darko, Schempp, Florence, Cheikh-Ali, Zakaria, Bode, Helge B |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578411/ https://www.ncbi.nlm.nih.gov/pubmed/26425196 http://dx.doi.org/10.3762/bjoc.11.152 |
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