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Pushing the Limits of Neutral Organic Electron Donors: A Tetra(iminophosphorano)-Substituted Bispyridinylidene

A new ground-state organic electron donor has been prepared that features four strongly π-donating iminophosphorano substituents on a bispyridinylidene skeleton. Cyclic voltammetry reveals a record redox potential of −1.70 V vs. saturated calomel electrode (SCE) for the couple involving the neutral...

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Detalles Bibliográficos
Autores principales: Hanson, Samuel S, Doni, Eswararao, Traboulsee, Kyle T, Coulthard, Graeme, Murphy, John A, Dyker, C Adam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4581462/
https://www.ncbi.nlm.nih.gov/pubmed/26213345
http://dx.doi.org/10.1002/anie.201505378