Protonation state of the Cu(4)S(2) Cu(Z) site in nitrous oxide reductase: redox dependence and insight into reactivity

Spectroscopic and computational methods have been used to determine the protonation state of the edge sulfur ligand in the Cu(4)S(2) Cu(Z) form of the active site of nitrous oxide reductase (N(2)OR) in its 3Cu(I)Cu(II) (1-hole) and 2Cu(I)2Cu(II) (2-hole) redox states. The EPR, absorption, and MCD sp...

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Detalles Bibliográficos
Autores principales: Johnston, Esther M., Dell'Acqua, Simone, Pauleta, Sofia R., Moura, Isabel, Solomon, Edward I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4583207/
https://www.ncbi.nlm.nih.gov/pubmed/26417423
http://dx.doi.org/10.1039/c5sc02102b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4583207/
https://www.ncbi.nlm.nih.gov/pubmed/26417423
http://dx.doi.org/10.1039/c5sc02102b

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