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MM quadruply bonded complexes supported by vinylbenzoate ligands: synthesis, characterization, photophysical properties and application as synthons

From the reactions between M(2)(T(i)PB)(4) compounds and meta and para-vinylbenzoic acids (2 equiv.) in toluene at room temperature the compounds trans-M(2)(T(i)PB)(2)L(2), where L = m-vinylbenzoate 1A (M = Mo) and 1B (M = W) and T(i)PB = 2,4,6-triisopropylbenzoate, and where L = p-vinylbenzoate 2A...

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Detalles Bibliográficos
Autores principales: Brown-Xu, Samantha E., Chisholm, Malcolm H., Durr, Christopher B., Spilker, Thomas F., Young, Philip J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4583209/
https://www.ncbi.nlm.nih.gov/pubmed/26417424
http://dx.doi.org/10.1039/c4sc02542c