1,4-Addition of TMSCCl(3) to Nitroalkenes: Efficient Reaction Conditions and Mechanistic Understanding

Improved synthetic conditions allow preparation of TMSCCl(3) in good yield (70 %) and excellent purity. Compounds of the type NBu(4)X [X=Ph(3)SiF(2) (TBAT), F (tetrabutylammonium fluoride, TBAF), OAc, Cl and Br] act as catalytic promoters for 1,4-additions to a range of cyclic and acyclic nitroalken...

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Detalles Bibliográficos
Autores principales: Wu, Na, Wahl, Benoit, Woodward, Simon, Lewis, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4586478/
https://www.ncbi.nlm.nih.gov/pubmed/24849249
http://dx.doi.org/10.1002/chem.201402394

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4586478/
https://www.ncbi.nlm.nih.gov/pubmed/24849249
http://dx.doi.org/10.1002/chem.201402394

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