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A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes

N-Phosphine oxide substituted imidazolylidenes (PoxIms) have been synthesized and fully characterized. These species can undergo significant changes to the spatial environment surrounding their carbene center through rotation of the phosphine oxide moiety. Either classical Lewis adducts (CLAs) or fr...

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Detalles Bibliográficos
Autores principales: Hoshimoto, Yoichi, Kinoshita, Takuya, Ohashi, Masato, Ogoshi, Sensuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4600235/
https://www.ncbi.nlm.nih.gov/pubmed/26315680
http://dx.doi.org/10.1002/anie.201505974