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A Strategy to Control the Reactivation of Frustrated Lewis Pairs from Shelf-Stable Carbene Borane Complexes
N-Phosphine oxide substituted imidazolylidenes (PoxIms) have been synthesized and fully characterized. These species can undergo significant changes to the spatial environment surrounding their carbene center through rotation of the phosphine oxide moiety. Either classical Lewis adducts (CLAs) or fr...
Autores principales: | Hoshimoto, Yoichi, Kinoshita, Takuya, Ohashi, Masato, Ogoshi, Sensuke |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4600235/ https://www.ncbi.nlm.nih.gov/pubmed/26315680 http://dx.doi.org/10.1002/anie.201505974 |
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