Boryl (Hetero)aryne Precursors as Versatile Arylation Reagents: Synthesis through C–H Activation and Orthogonal Reactivity

(Pinacolato)boryl ortho-silyl(hetero)aryl triflates are presented as a new class of building blocks for arylation. They demonstrate unique versatility by delivering boronate or (hetero)aryne reactivity chemoselectively in a broad range of transformations. This approach enables the unprecedented post...

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Detalles Bibliográficos
Autores principales: Demory, Emilien, Devaraj, Karthik, Orthaber, Andreas, Gates, Paul J, Pilarski, Lukasz T
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4600243/
https://www.ncbi.nlm.nih.gov/pubmed/26270451
http://dx.doi.org/10.1002/anie.201503152

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4600243/
https://www.ncbi.nlm.nih.gov/pubmed/26270451
http://dx.doi.org/10.1002/anie.201503152

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