Phase Diagram and Transformations of Iron Pentacarbonyl to nm Layered Hematite and Carbon-Oxygen Polymer under Pressure

We present the phase diagram of Fe(CO)(5), consisting of three molecular polymorphs (phase I, II and III) and an extended polymeric phase that can be recovered at ambient condition. The phase diagram indicates a limited stability of Fe(CO)(5) within a pressure-temperature dome formed below the liqui...

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Detalles Bibliográficos
Autores principales: Ryu, Young Jay, Kim, Minseob, Yoo, Choong-Shik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4601022/
https://www.ncbi.nlm.nih.gov/pubmed/26456761
http://dx.doi.org/10.1038/srep15139

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4601022/
https://www.ncbi.nlm.nih.gov/pubmed/26456761
http://dx.doi.org/10.1038/srep15139

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