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Phase Diagram and Transformations of Iron Pentacarbonyl to nm Layered Hematite and Carbon-Oxygen Polymer under Pressure
We present the phase diagram of Fe(CO)(5), consisting of three molecular polymorphs (phase I, II and III) and an extended polymeric phase that can be recovered at ambient condition. The phase diagram indicates a limited stability of Fe(CO)(5) within a pressure-temperature dome formed below the liqui...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Nature Publishing Group
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4601022/ https://www.ncbi.nlm.nih.gov/pubmed/26456761 http://dx.doi.org/10.1038/srep15139 |