Organocatalyzed Trifluoromethylation of Ketones and Sulfonyl Fluorides by Fluoroform under a Superbase System

Fluoroform (HCF(3), HFC-23) is a side product in the manufacture of polytetrafluoroethylene (Teflon). Despite its attractive properties, taming HCF(3) for trifluoromethylation is quite problematic owing to its low acidity and the lability of the naked trifluoromethyl carbanion generated from HCF(3)....

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Detalles Bibliográficos
Autores principales: Okusu, Satoshi, Hirano, Kazuki, Tokunaga, Etsuko, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley & Sons, Ltd 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4608523/
https://www.ncbi.nlm.nih.gov/pubmed/26491635
http://dx.doi.org/10.1002/open.201500160

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4608523/
https://www.ncbi.nlm.nih.gov/pubmed/26491635
http://dx.doi.org/10.1002/open.201500160

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