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Energetics of proton release on the first oxidation step in the water-oxidizing enzyme

In photosystem II (PSII), the Mn(4)CaO(5) cluster catalyses the water splitting reaction. The crystal structure of PSII shows the presence of a hydrogen-bonded water molecule directly linked to O4. Here we show the detailed properties of the H-bonds associated with the Mn(4)CaO(5) cluster using a qu...

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Detalles Bibliográficos
Autores principales: Saito, Keisuke, William Rutherford, A., Ishikita, Hiroshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Pub. Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4617610/
https://www.ncbi.nlm.nih.gov/pubmed/26442814
http://dx.doi.org/10.1038/ncomms9488